|
KER
828 MSDS |
|
KUMHO
P&B CHEMICALS,
INC. |
Material
Safety Data
Sheet |
KER
Epoxy Resins
KER
828 |
Date:
01 June,1999 |
1.
IDENTIFICATION
OF THE SUBSTANCE/PREPARATION
AND COMPANY |
·Product
name :
KER 828
·Product
Code : L123A
·Product
type : RESIN
LIQUID
·Supplier
: Kumho
P&B Chemicals,
Inc.
·Address
: Korea
·Contact
numbers :
82-2-6303-0114
·Emergency
telephone number
: 82-2-6303-0114
·Other information
: http://www.kpb.co.kr
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2.
C0MPOSITION/INFORMATION
ON INGREDIENTS |
 |
|
Substance
chemical family:
Reaction product
of bisphenol
A and epichlorohydrin
CAS number:
25068-38-6
Other
information:
Liquid epoxy
resin |
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3.
HAZARDS
IDENTIFICATION |
 |
|
Human health
hazards:
Irritating to
eyes and skin.
May cause sensitization
by skin contact.
Safety
hazards:
Not classified
as flammable
but will burn.
Environmental
hazards:
Toxic to
aquatic organisms.
May cause
long term
adverse effects
in the aquatic
environment. |
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4.
FIRST
AID
MEASURES |
 |
|
Symptoms
and effects:
Irritation of
the skin and
eyes
First
Aid - Inhalation:
No specific
measures.
First
Aid - Skin:
DO NOT DELAY.
Remove contaminated
clothing.
Wash skin
with water
using soap
if available.
If persistent
irritation
occurs, obtain
medical attention.
First
Aid - Eye:
DO NOT DELAY.
Flush eye
with water.
If persistent
irritation
occurs, obtain
medical attention.
First
Aid - Ingestion:
Do not induce
vomiting.
In the unlikely
event of ingestion,
obtain medical
attention
immediately
Advice
to physicians:
If skin sensitization
has developed
and a causal
relationship
has been confirmed
further exposure
should not
be allowed. |
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5.
FIRE
FIGHTING
MEASURES |
 |
|
Specific
hazards:
Not classified
as flammable
but will burn.
Carbon monoxide
may be evolved
if incomplete
combustion
occurs.
Extinguishing
media - small
fires:
Dry chemical
powder, carbon
dioxide, foam,
water spray
or fog,sand
or earth.
Extinguishing
media - large
fires:
Foam, water
spray or fog.
Unsuitable
extinguishing
media:
Water in
a jet.
Protective
equipment:
Full protective
clothing and
self-contained
breathing
apparatus.
Other
Information:
Keep adjacent
containers
cool by spraying
with water. |
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6.
ACCIDENTAL
RELEASE
MEASURES |
 |
|
Personal
precautions:
Avoid contact
with skin, eyes
and clothing.
Personal
protection:
Wear protective
clothing specified
for normal
operations
(see Section
8).
Environmental
precautions:
Prevent contamination
of soil and
water.
Prevent from
spreading
or entering
into drains,
ditches or
rivers by
using sand,
earth, or
other appropriate
barriers.
If material
enters drains,
it should
be pumped
out into an
open vessel.
Emergency
services may
need to be
called to
assist in
this operation.
Clean-up
methods -
small spillage:
Absorb or
contain liquid
with sand,
earth or spill
control material.
Shovel up
and place
in a labeled,
sealable container
for subsequent
safe disposal.
Scrub contaminated
surfaces with
a detergent
solution.
Retain washings
as contaminated
waste. Put
leaking containers
in a labeled
drum or overdrum
Clean-up
methods -
large spillage:
Transfer
to a labeled
container
for product
recovery or
safe disposal.
Otherwise
treat as for
small spillage.
Other
information:
See Section
13 for information
on disposal. |
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7.
HANDLING
AND
STORAGE |
 |
|
Handling:
Avoid contact
with skin, eyes
and clothing.
Storage:
Keep container
tightly closed
and dry. Palletized
loads should
be stacked
to a maximum
of 4 high.
Storage
temperatures:
Ambient. |
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8.
EXPOSURE
CONTROLS/PERSONAL
PROTECTION |
 |
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Occupational
exposure standards:
None established.
Respiratory
protection:
Not normally
required.
In a confined
space, wear
half mask
respirator
with organic
vapor cartridge
and built-in
particulate
filter NPF
20 (gas only).
If product
is applied
by spraying,
wear self-contained
breathing
apparatus.
Hand protection:
Nitrile rubber
gloves or
butyl rubber
gloves, gauntlet
type.
Eye protection:
Monogoggles.
Body protection:
Standard
issue work
clothes.
Safety boots
- chemical
resistant
without lace
holes. |
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9.
PHYSICAL
AND
CHEMICAL |
 |
|
Physical
state:
Colour:
Odour:
pH:
Boiling
point:
Vapor
pressure
Density:
Dynamic
viscosity:
Electrical
conductivity:
Flash
point:
Auto-ignition
temperature:
Solubility
in water:
n-octanol/water
partition
coefficient:
|
Liquid
Pale yellow
Slight
circa
7
>
200¡É.
<
0.01
Pa @
20 °C
1160
kg/m3
@ 25
°C
12-14
Pa.s
@ 25
°C
1150
pS/m
@ 22
°C
>
200¡É
(PMCC)
>
300
°C
circa
0.009
kg/m3
@ 23
°C
log
Pow
>
3 |
|
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10.
STABILITY/REACTIVITY
|
 |
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Stability:
Stable under
normal use conditions.
Reacts with
strong oxidizing
agents. Polymerizes
exothermically
with amines,
mercaptans and
Lewis acids
at ambient temperature
and above.
Polymerizes
in contact
with caustic
soda. Reacts
exothermically
with bases
(eg caustic
soda), ammonia,
primary and
secondary
amines, alcohols
and acids.
Conditions
to avoid:
Caustic soda
can induce
a vigorous
polymerization
at temperatures
around 200
°C.
Materials
to avoid:
Strong oxidizing
agents. Caustic
soda.
Hazardous
decomposition
products:
Hazardous
decomposition
products are
not expected
to form during
normal storage. |
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11.
TOXICOLOGICAL
INFORMATION
|
 |
|
Basis
for
assessment:
Acute
toxicity
- oral:
Acute
toxicity
- dermal:
Eye
irritation:
Skin
irritation:
Respiratory
irritation:
Skin
sensitization:
Carcinogenicity:
Mutagenicity:
|
Information
given
is based
on product
data.
LD50 >
2000 mg/kg
LD50 >
2000 mg/kg
Irritant
Irritant
Not irritating
Skin sensitizer
A recent
review
of the
available
data by
the International
Agency
for Research
on Cancer
(IARC),
has concluded
that DGEBPA
is not
classifiable
as to
its carcinogenicity
Positive
in in
vitro,
but negative
in in
vivo assays.
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12.
ECOLOGICAL
INFORMATION |
 |
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Basis
for
assessment:
Mobility:
Persistence/degradability:
Bioaccumulation:
Acute
toxicity
- fish:
Sewage
treatment:
|
Incomplete
ecotoxicological
data are
available
for this
Substance.
Sinks
in water.
Not readily
biodegradable.
IHas the
potential
to bioaccumulate.
Toxic,
1 <
LC50 ¡Â
10 mg/l.
Toxic,
EC50 >1-10
mg/l,
to organisms
in sewage
treatment
plants. |
|
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13.
DISPOSAL
CONSIDERATIONS |
 |
|
Precautions:
See Section
8. Refer to
Section 7 before
handling the
product or containers.
Waste
disposal:
Recover or
recycle if
possible.
Otherwise
incineration
or dispose
to licensed
disposal contractor.
Product
disposal:
Recover or
recycle if
possible.
Otherwise
incineration
or dispose
to licensed
disposal contractor.
Container
disposal:
Drain container
thoroughly.
Rinse three
times with
suitable solvent.
Treat rinsings
as for product
disposal.
After draining,
vent in a
safe place
away from
sparks and
fire. Send
to drum recoverer
or metal reclaimer.
Local
legislation: |
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14.
TRANSPORT
INFORMATION
|
 |
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IADR/RID
Class/Item:
ADR/RID
Symbol:
ADR/RID
Kemler
Number:
ADR/RID
Proper
Shipping
Name:
Local
regulations: |
Not dangerous
for conveyance
under
UN, IMO
and IATA/ICAO
codes.
9/II(C)
Miscellaneous
dangerous
substances.
90
3082
Environmentally
Hazardous
Substance,
Liquid,
N.O.S
(Epoxy
Resin)
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15.
REGULATORY
INFORMATION |
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EC
Label
name:
EC Classification:
EC Symbols:
EC Risk
phrases:
EC Safety
phrases:
EINECS
(EC):
EC Annex
I number:
MITI
(Japan):
TSCA
(USA):
AICS
(Australia):
DSL
(Canada):
National
legislation:
|
Epoxy
resin
(Number
Average
Molecular
Weight
< 700)
Irritant.
Dangerous
for the
environment.
Xi,N
R36/38
Irritating
to eyes
and skin.
R43 May
cause
sensitization
by skin
contact.
R51/53
Toxic
to aquatic
organisms,
may cause
long-term
adverse
effects
in the
aquatic
environment.
S24 Avoid
contact
with skin.
S26 In
case of
contact
with eyes,
rinse
immediately
with plenty
of water
and seek
medical
advice.
S28
After
contact
with
skin;
wash
immediately
with
plenty
of soap
and
water.
S37/39
Wear
suitable
gloves
and
eye/face
protection.
S61
Avoid
release
to the
environment.
Refer
to special
instructions
/Safety
data
sheets.
Polymer
exempt
603-074-00-8
Listed
Listed
Listed
Listed
Listed
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16.
OTHER
INFORMATION |
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Uses
and restrictions:
Compositions
for the building
and civil engineering
industries e.g.
flooring compounds,
adhesives, mortars
and grouts,
solvent free
and high-solids
coatings, laminating
binders. |
DISCLAIMER:
This information
is based on
our current
knowledge and
is intended
to describe
the product
for the purposes
of health, safety
and environmental
requirements
only. It should
not therefore
be construed
as guaranteeing
any specific
property of
the product. |
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